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Role of Supramolecular Strucutres in Mechanisms of Catalytic Oxidation and Action of Ni(Fe)ARD Dioxygenases on Model Systems

Ludmila Matienko1, Vladimir Binykov1, Elena Mil1, Gennady Zaikov1
Affiliation: 
1 The Federal State Budget Institution of Science, Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Russian Federation matienko@sky.chph.ras.ru
DOI: 
https://doi.org/10.23939/chcht14.03.304
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Keywords:

Abstract: 
The AFM technique was used to research the possibility of the supramolecular structures formation due to H-bonds based on Ni(Fe)(acac)n-systems, that are catalysts of alkylarens oxidations and also models Ni(Fe)ARD dioxygenases: {M(acac)n+L2+L3} triple systems (M=NiII, FeIII , L2 = NMP (NMP = N-methyl-2-pirrolidone), L-histidine, L3 = PhOH, L-tyrosine), n = 2, 3). Role of H-bonding and supramolecular structures in alkylarens oxidations, catalyzed with Ni(or Fe) complexes catalysts, and also role of supramolecular structures and Tyr-fragment in mechanisms of Ni(Fe)ARD-actions is discussed.
References: 

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