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The Sulfonation of 3,5,7,3’,4’-Pentahydroxyflavone and Non-Linear-Optical Activity of its Sulfonic Derivatives

Dmytro Mishurov
Affiliation: 
1 National Technical University «Kharkiv Polytechnic Institute» 2, Kyrpychova St., 61002 Kharkiv, Ukraine mishurov@kpi.kharkov.ua
DOI: 
https://doi.org/10.23939/chcht13.01.033
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Keywords:

Abstract: 
Synthesis of sulfoquercetin and studies of its structure and nonlinear properties have been carried out. Using quantum-chemical simulations, 13С and HSQC NMR spectrometry, FTIR spectroscopy it was shown that a sulphonic group occurs in C8 location of quercetin. Molecular first hyperpolarizability of the obtained 8-sulfoquercetin was studied. It was shown that 8-sulfoquercetin can be used for creation the new polymer NLO materials on its basis.
References: 

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