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Target Synthesis of Functional Biocompatible Nanocomposites with “Core-Shell” Structure

Alexander Zaichenko1, Nataliya Mitina1, Olesia Miagkota1, Orest Hevus1, Rortyslav Bilyi2, Rostyslav Stoika2, Olena Payuk1, Zoriana Nadashkevych1, Anatoliy Voloshinovskii3
Affiliation: 
1 Lviv Polytechnic National University, 12, S. Bandera St., 79013 Lviv, Ukraine 2 Institute of Cell Biology NAS of Ukraine, 14/16 Drahomanov St., 79005 Lviv, Ukraine 3 Ivan Franko National University of Lviv, 8, Kyryla i Mefodiya St., 79005 Lviv, Ukraine zaichenk@polynet.lviv.ua
DOI: 
https://doi.org/10.23939/chcht12.01.029
AttachmentSize
PDF icon full_text.pdf1.91 MB
Abstract: 
Metal-complex macroinitiators were successfully applied for the synthesis of polymer nanocomposites with core-shell structure by two-stage water dispersed polymerization. On the first stage, formation of monodispersed polymer particles of desired size and functionality is achieved by target variation of macroinitiator concentration, content of metal cations in its structure, and pH of medium. Initiation of grafted polymerization from the surface of seeded particles is provided by residual peroxide moieties of macroinitiator.
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