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Headspace Analysis of Aroma Compounds Using Porous Adsorbents

Tamara Misharina
Affiliation: 
N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 Kosygin str., Moscow, 119334 Russia; tmish@rambler.ru
DOI: 
https://doi.org/10.23939/chcht05.03.347
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Keywords:

Abstract: 
A novel procedure is developed for the quantitative determination of volatile compounds in the vapour phase over samples. Substances were extracted and preconcentrated from the headspace on porous polymer adsorbents under the conditions of thermodynamic equilibrium, followed by back extraction from the adsorbent using organic solvents. The final monitoring was performed by capillary gas chromatography with an internal standard. The influence of adsorption time and the concentration of substances in an aqueous solution on the degree of extraction were also studied; linear correlations between the quantities of substances in the gas and aqueous phases were found. The method was used for the determination of volatile substances in the gas phase over liquid and solid matrixes of different composition.
References: 

[1] Wilson C. and Brown W.: J. Sens. Stud., 1997, 21, 69.

[2] Seurve A., Diaz M. and Voilley A.: J. Agric. Food Chem., 2000, 48, 4296.
https://doi.org/10.1021/jf990825w

[3] Golovnya R. and Misharina T.: Zh. Anal. Khim., 1981, 36, 1390.

[4] Ettre L.: [in:] Rouseff R. and Cadwallader K. (Eds.) Headspace Analysis of Food and Flavours: Theory and Practice. Academic Plenum, New York 2001.
https://doi.org/10.1007/978-1-4615-1247-9

[5] Nongonierma A., Cayot P., Le Quere J. et al.: Food Rev. Int., 2006, 22, 51.
https://doi.org/10.1080/87559120500379951

[6] Zhu J. and Chai X.-C.: Curr. Anal. Chem., 2005, 1, 79.
https://doi.org/10.2174/1573411052948488

[7] Flamini G.: Curr. Anal. Chem., 2007, 3, 149.

[8] Angerosa F., Servili M., Selvaggini R. et al.: J. Chromatogr. A, 2004, 1054, 17.
https://doi.org/10.1016/S0021-9673(04)01298-1

[9] Arthur C. and Pawliszyn J.: Anal. Chem., 1990, 62, 2145.
https://doi.org/10.1021/ac00218a019

[10] Baltussen E., Sandra P., David F. and Cramers C.: J. Microcolumn Sep., 1999, 11, 737.
https://doi.org/10.1002/(SICI)1520-667X(1999)11:10<737::AID-MCS7>3.0.CO;2-4

[11] Vichi S., Castellote A., Pizzale L. et al.: J. Chromatogr. A, 2003, 983, 19.
https://doi.org/10.1016/S0021-9673(02)01691-6

[12] Bellesia F., Pinetti U., Rinaldi R. et al.: Food Chem., 2003, 83, 55.
https://doi.org/10.1016/S0308-8146(03)00037-2

[13] Ruiz J., Cava R., Ventanas J. and Jensen M.: J. Agric. Food Chem., 1998, 46, 4688.
https://doi.org/10.1021/jf980139h

[14] Demyttenaere M., Sanchez Martinez J., Verhe R. et al.: J. Chromatogr. A, 2003, 985, 221.
https://doi.org/10.1016/S0021-9673(02)01471-1

[15] Tienpont B., David F., Bicchi C. and Sandra P.: J. Microcolumn Sep., 2000, 12, 577.
https://doi.org/10.1002/1520-667X(2000)12:11<577::AID-MCS30>3.3.CO;2-H

[16] Griffit S., Wyllie S. and Markham J.: J. Chromatogr. A, 1999, 894, 221.
https://doi.org/10.1016/S0021-9673(99)01009-2

[17] Zhu P.-L., Liu C.-L. and Liu M.-C.: J. Chromatogr. A, 2003, 988, 25.
https://doi.org/10.1016/S0021-9673(02)01994-5

[18] Zhang Z. and Pawliszyn J.: J. Anal. Chem., 1993, 65, 1843.
https://doi.org/10.1021/ac00062a008

[19] Engels W., Dekker R., Jong C. et al.: Int. Dairy J., 1997, 7, 255.
https://doi.org/10.1016/S0958-6946(97)00003-4

[20] Guitard R., Puigdemont A. and Arboix A.: J. Chromatogr., 1989, 491, 271.
https://doi.org/10.1016/S0378-4347(00)82845-5

[21] Seure A., Philippe E., Rochard S. and Voilley A.: Food Res. Int., 2007, 40, 480.
https://doi.org/10.1016/j.foodres.2006.09.005

[22] Guichard E.: Food Rev. Int., 2002, 18, 49.
https://doi.org/10.1081/FRI-120003417

[23] Jouquand C., Ducruet V. and Giampaoli P.: Food Chem., 2004, 85, 467.
https://doi.org/10.1016/j.foodchem.2003.07.023

[24] Savary G., Guichard E., Doublier J.-L. and Cayot N.: Food Res. Int., 2006, 39, 372.
https://doi.org/10.1016/j.foodres.2005.09.002

[25] Ettre L., Welter C. and Kolb B.: Chromatographia, 1993, 35, 73.
https://doi.org/10.1007/BF02278560

[26] Athes V., Pena Y., Lillo M. et al.: J. Agric. Food Chem., 2004, 52, 2021.
https://doi.org/10.1021/jf0350257

[27] Bylaite E., Ilgunaite Z., Meyer A. and Alder-Nissen M.: J. Agric. Food Chem., 2004, 52, 3542.
https://doi.org/10.1021/jf0354996